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Creators/Authors contains: "Newhouse, Timothy R"

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  1. ; ; ; ; ; ; ; ; ; ; et al (, Nature Communications)
    Free, publicly-accessible full text available December 1, 2025
  2. ; ; ; (, Journal of the American Chemical Society)
    Full Text Available 
  3. ; ; (, Organic Letters)
    Full Text Available 
  4. ; ; ; (, Journal of the American Chemical Society)
    Full Text Available 
  5. ; ; ; (, Chirality)
    Abstract This manuscript describes predicted NMR shifts for the limonoid natural product xylogranatin F. The1H and13C NMR shifts of four diastereomers were evaluated by GIAO and hybrid DFT/parametric DU8+ methods. The results of the1H and13C NMR calculations for both the GIAO method and the DU8+ calculations suggest the revised structure that was recently reassigned by chemical synthesis. Furthermore, we show that while DU8+ provides superior accuracy with less computation time, GIAO points to the correct structure with more distinguishable data in this case study. 
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  6. ; ; ; ; (, Angewandte Chemie International Edition)
    Abstract Meroterpenes derived from dimethylorsellinic acid (DMOA) and farnesyl pyrophosphate have attracted much biosynthetic attention, yet only recently have synthetic solutions to any family members appeared. A key point of divergence in DMOA‐derived meroterpene biosynthesis is the protoaustinoid A carbocation, which can be diverted to either the berkeleyone, andrastin, or terretonin structural classes by cyclase‐controlled rearrangement pathways. Shown herein is that the protoaustinoid bicyclo[3.3.1]nonane nucleus can be reverted to either andrastin or terretonin ring systems under abiotic reaction conditions. The first total syntheses of members of these natural product families are reported as their racemates. 
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